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Updated: Dec 12, 2025

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

Published on: July 28, 2018

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カーボニル誘導型アリファティック・フローリネーション: 特殊なタイプの水素原子移転がノリッシュIIに勝る

Fereshte Ghorbani1, Stefan Andrew Harry1, Joseph N Capilato1

  • 1Department of Chemistry, Johns Hopkins University, 3400 N. Charles Street, Baltimore, Maryland 21218, United States.

Journal of the American Chemical Society
|August 14, 2020
PubMed
まとめ

この研究では,光刺激されたエノンとケトンは,ノリッシュ抽象ではなく,分子間水素原子移転 (HAT) による局所選択C-H化を直接行います. この異常なHATプロセスで,光プロモーターは化学的に変化する.

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