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Updated: Dec 11, 2025

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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小さなフォスフィンリガンドは,ニッケルでAr-OのAr-Cl結合に対する選択的酸化添加を可能にします

Emily D Entz1, John E A Russell1, Leidy V Hooker1

  • 1Department of Chemistry and Biochemistry, Montana State University, Bozeman, Montana 59717, United States.

Journal of the American Chemical Society
|August 18, 2020
PubMed
まとめ

この研究は,アリル塩化物の制限を克服して,フェノール誘導体の新しいニッケル触媒スズキ-ミヤウラ結合を導入します. トリメチルフォスフィン (PMe3) は,選択的なC-O結合活性化を可能にし,クロスカップリング反応の重要な進歩である.

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