チラル結合塩基安定カルボキシル酸のモジュール設計:触媒エナチオセレクティブ [4 + 2] アセタルのサイクル添加

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Updated: Dec 11, 2025

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

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Zhengbo Zhu1, Minami Odagi1,2, Nantamon Supantanapong1

  • 1Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, Florida 32611, United States.

Journal of the American Chemical Society
|August 25, 2020
PubMed
まとめ

アミノアルコールから派生した新しいキラルカルボキシル酸触媒は,キラルリン酸に匹敵する酸性を提供します. アニオン結合の安定化により,ポリサイクルクロマーンの合成に高度なエナチオセレクティブの [4+2] サイクロアディションが可能である.

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