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Updated: Dec 10, 2025

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
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Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes

Published on: September 12, 2018

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エナチオセレクティブ・アリルイオイド・カタライズド・ワグナー・ミールウェイン再配列

Hayden A Sharma1, Katrina M Mennie1, Eugene E Kwan1

  • 1Department of Chemistry & Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.

Journal of the American Chemical Society
|August 27, 2020
PubMed
まとめ

この研究は,アルキルイオダンを用いたエナチオセレクティブカルボカチオンの再配置のための新しい触媒法を導入しています. ワグナー-ミールウェインの非対称的な再配置は,異なるメカニズムを通じて貴重な1,3-二酸化炭素濃縮化合物へのアクセスを提供します.

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