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Updated: Dec 10, 2025

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
14:44

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR

Published on: December 16, 2013

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NMRによる金属タンパク質における金属結合部位における調整球のピコメーター解像度構造

Andrea Bertarello1,2, Ladislav Benda1, Kevin J Sanders1

  • 1Université de Lyon, Centre de RMN à Très Hauts Champs, FRE 2034 CNRS/Université Claude Bernard Lyon 1/ENS Lyon, 5 rue de la Doua, Villeurbanne 69100, France.

Journal of the American Chemical Society
|September 2, 2020
PubMed
まとめ

この研究では,高解像度メタロプロテイン活性部位構造を達成するために,マジック・アングル・スピニング・核磁共鳴 (MAS NMR) と計算技術を組み合わせた新しい方法が導入されています. このアプローチはタンパク質の機能を理解するために不可欠な金属の協調幾何学を正確に決定します

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Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For instance, the four valence electrons of carbon overlap with electrons from four hydrogen atoms to form CH4. The one valence electron leaves sodium and adds to the seven valence electrons of chlorine to form the ionic formula unit NaCl (Figure 1a). Transition metals do not normally bond in this fashion. They primarily form coordinate covalent bonds, a...
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