P (III) /P (V) - アリルボロン酸とエステルの触媒メチラミネーション:メチラミンサロゲートとしてのニトロメタンとの還元性C-N結合

Gen Li1, Ziyang Qin1, Alexander T Radosevich1

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

PubMed
まとめ

研究者は,ニトロメタンの直接的なN-アリレーションのための新しい有機リン触媒方法を開発しました. この効率的なC-N結合はメチラミノ置換の芳香物質を作り,同位体として標識されたN-メチラニリンの合成を可能にします.

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