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Updated: Dec 9, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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PIII/PV合成サイクルにおけるラウンドトリップ酸化添加,リガンドメタテシス,還元性除去

Soohyun Lim1, Alexander T Radosevich1

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|September 10, 2020
PubMed
まとめ

この研究は,新しいリン酸トライアミドを用いたアリルC−F結合置換のための合成サイクルを導入する. このサイクルには,酸化添加,リガンド転移,還元性除去が含まれ,メイングループサイトで重要なメカニズム的ステップを示しています.

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