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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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鉄基スピンクロスオーバーによる有機ダイラディカル性質の可逆的な切り替え

Airi Kawamura1, Jiaze Xie1, Jan-Niklas Boyn1

  • 1Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, United States.

Journal of the American Chemical Society
|September 19, 2020
PubMed
まとめ

研究者は,無機のスピントランジションが有機のダイラジカル特性を制御する方法を示しています. テトラチアフルバレン-2,3,6,7-テトラチオラートリガンドを持つ二鉄複合体は,熱誘発のスピンクロスオーバーを示し,ダイラジカル特性を生成する.

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