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Updated: Dec 5, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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CO との金属無カルベン触媒カルボニレーション反応の実現

Jesse L Peltier1, Eder Tomás-Mendivil1,2, Daniel R Tolentino1

  • 1UCSD-CNRS Joint Research Chemistry Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, California 92093-0358, United States.

Journal of the American Chemical Society
|October 15, 2020
PubMed
まとめ

安定したシングレット二性カルベンは一酸化炭素 (CO) を活性化させ,オキノンの炭化化反応を循環炭酸に触媒化する. この発見は,炭化反応のための金属のない代替案を提供します.

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