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Updated: Dec 3, 2025

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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トリフローロメチラレンのC (sp3) -F結合をBis (NHC) ニッケル (0) 複合体を使って割る

Hiroaki Iwamoto1, Hiroto Imiya1, Masato Ohashi2

  • 1Department of Applied Chemistry, Osaka University, Suita, Osaka 565-0871, Japan.

Journal of the American Chemical Society
|October 28, 2020
PubMed
まとめ

この研究では,ニッケル ((0) コンプレックスがC ((sp3) -F結合をトリフローロメチラレンで初めて分裂することを実証した. この反応性により,これらの複雑な化合物に対する新しい触媒性水酸化法が可能になります.

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