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Updated: Dec 1, 2025

In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework
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In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework

Published on: February 1, 2020

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高度に選択的なCO2のメタノールへの水素化に対するIn2O3/ZrO2に対する強い電子酸化サポート相互作用

Chengsheng Yang1, Chunlei Pei1, Ran Luo1

  • 1Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology; Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Weijin Road 92, Tianjin 300072, China.

Journal of the American Chemical Society
|November 6, 2020
PubMed
まとめ

インジウム酸化物 (In2O3) とモノクリニックジルコニア (m-ZrO2) の強い電子相互作用は,異質な触媒におけるメタノールの選択性を高めます. この発見は,高度な水素化触媒の開発を導いた.

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Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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Introduction
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Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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