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Updated: Dec 1, 2025

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s-cis,s-cis-Dihydroxycarbene, 新しい [CH2O2] 中間物質の識別と反応性

Henrik Quanz1, Bastian Bernhardt1, Frederik R Erb1

  • 1Institute of Organic Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, D-35392 Giessen, Germany.

Journal of the American Chemical Society
|November 9, 2020
PubMed
まとめ

研究者らは初めてダイヒドロキシカルベン (1cc) のs-cis,s-cisコンフォマーを作製した. この不安定なコンフォマーが 凍結温度で量子トンネルを介して 急速に別の形に変化します

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