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Updated: Nov 30, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
08:22

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization

Published on: August 6, 2018

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振動的に熱くて冷たい三重体 Di-π-メタン再配列の感受剤依存ダイナミクスと局所振動促進

Kai-Yuan Kuan1, Daniel A Singleton1

  • 1Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842, United States.

Journal of the American Chemical Society
|November 12, 2020
PubMed
まとめ

ベンゾバレレンの再配置における大きな分子内運動同位体効果 (KIE) は,低エネルギー感受剤を用いた重原子トンネリングと一致する. 高エネルギー感知器はより低いKIEを生成し,過剰な振動エネルギーによる熱い非統計的動態を示します.

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