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Updated: Nov 29, 2025

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
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[2,2](5,8) ピセノファネディエン:合成,構造分析,分子動力学,および可逆性内分子構造変換

Min-Chih Tang1, Yu-Chen Wei2, Yen-Chen Chu1

  • 1Department of Chemistry, National Cheng Kung University, 70101 Tainan, Taiwan.

Journal of the American Chemical Society
|November 19, 2020
PubMed
まとめ

研究者はダイブロモフェン誘導体の効率的な合成を開発し,新しいピケノファンを生み出した. これらの分子は,構造的変異の影響を受けた二重放出とエクシマー形成を含むユニークな光物理的特性を表しています.

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The Cope rearrangement is classified as a [3,3] sigmatropic shift in 1,5-dienes, leading to a more stable, isomeric 1,5-diene. The reaction involves a concerted movement of six electrons, four from two π bonds and two from a σ bond, via an energetically favorable chair-like transition state.
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