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Updated: Nov 29, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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ラジカル・ポラー・クロスオーバーメカニズムによるアルキルブロミドによるアルケンの電気還元カルボ機能化

Wen Zhang1, Song Lin1

  • 1Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14850, United States.

Journal of the American Chemical Society
|November 24, 2020
PubMed
まとめ

電気化学は,ラジカル・ポラー・クロスオーバー経路を通じてアルケンの還元機能化を可能にします. この方法は,単純な条件を用いて高選択性で複雑な分子間カルボフォーマル化,水素アルキル化,およびカルボカルボキシル化を実現します.

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