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強いSi-Cl結合の活性化によるラジカルシリレーションに対する電還元アプローチ

Lingxiang Lu1, Juno C Siu1, Yihuan Lai1

  • 1Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, United States.

Journal of the American Chemical Society
|December 8, 2020
PubMed
まとめ

研究者は,クロロシランからシリルラジカルを生成する新しい電還元方法を開発しました. この過渡金属のないアプローチは,合成化学を進めて,効率的なアルケンのシリレーション反応を可能にします.

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