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Updated: Nov 24, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

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P-C結合形成におけるロジウム複合体:ヒドリドリガンドの重要な役割

Víctor Varela-Izquierdo1, Ana M Geer1, Janeth Navarro1

  • 1Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC-Universidad de Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza, Spain.

Journal of the American Chemical Society
|December 28, 2020
PubMed
まとめ

この研究では,ロジウム触媒 [Rh (Tp) H (PMe3) (PPh2) ] がオレフィン水酸化を効果的に促進することを明らかにした. ハイドリガンドは,機能化されたホスファンを合成するためのP-CおよびH-C結合形成を促進する上で重要な役割を果たします.

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