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Updated: Nov 23, 2025

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
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Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method

Published on: July 19, 2019

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メカノフォアの活性化における同位体効果

Robert Nixon1, Guillaume De Bo1

  • 1Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom.

Journal of the American Chemical Society
|December 31, 2020
PubMed
まとめ

イソトープ置換はメカノフォア活性化を劇的に変化させた. デュテレーションは特定の反応経路を阻害し,機械化学における単純な運動学を超えたダイナミックな効果を明らかにした.

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