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Updated: Nov 22, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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エナチオセレクティブの逆電子需要 (3 + 2) パラジウム-オキシアリルのサイクロアディション,水素結合ドナーリガンドによって可能

Yin Zheng1, Tianzhu Qin1, Weiwei Zi1

  • 1State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.

Journal of the American Chemical Society
|January 6, 2021
PubMed
まとめ

この研究は,複雑な環系を合成するための新しいエナンチオセレクティブ (3 + 2) サイクロアディション反応を導入する. この方法は,パラジアム-オキシアリル種とニトロアルケンを用いて,複数のステレオセンターを持つサイクロペンタノンを効率的に生成します.

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