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Updated: Nov 20, 2025

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

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イリジウム触媒Z-レテントの非対称性アリル置換反応

Ru Jiang1, Lu Ding1, Chao Zheng1

  • 1State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.

Science (New York, N.Y.)
|January 22, 2021
PubMed
まとめ

この研究は,キラルZ-オレフィン合成のための新しいイリジウム触媒反応を導入する. この方法は,Z-オレフィン幾何学を保ちながら,隣接する四次ステレオセンターを作成し,重要な合成課題を克服します.

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