このページは機械翻訳されています。他のページは英語で表示される場合があります。View in English
単純な有機塩の自己組み立てから生じる複雑な構造
Riccardo Montis1,2, Luca Fusaro3, Andrea Falqui4,5
1School of Chemistry, University of Southampton, Southampton, UK. riccardo.montis@gmail.com.
Nature
|February 11, 2021
PubMed で要約を見る
まとめ
研究者らはシンプルな有機分子であるファムプリジン塩化物で新しいフランク・カスパル (FK) 段階を発見した. この発見は 複雑な自己組織化構造を 有機結晶で明らかにし 以前は小さな分子では 見られなかったのです
科学分野:
- 超分子化学
- 材料科学
- クリスタルグラフィー
背景:
- 分子自己組み立ては 自然のプロセスや素材の設計に 根本的な役割を果たします
- 微小な有機分子の自己組織化のルールを理解するのは 難題です
- 合金や柔らかい物質で知られているフランク・カスパー (FK) 段階は,複雑な構造である.
研究 の 目的:
- 単純なファムプリジン塩化塩の自己組み立て行動を調査する.
- 分子自己組み立てによって形成された新しい結晶構造を特定し,特徴づけること.
- 有機系における複合多面体群の形成を研究する.
主な方法:
- ファムプリジン塩化物の結晶化
- 結晶相の構造分析
- 前駆体密度の高い液体相の冷凍電子顕微鏡
主要な成果:
- ファムプリジン塩化物の4つの異なる結晶構造を特定した.
- 異様な2つのFK相を発見した.
- 先駆体液相における球状積層 (1.54.6 nm) を観測した.
- これらのFK相は,通常,小さな有機分子では見られない複雑性を表します.
さらに関連する動画
関連する概念動画
Ionic Crystal Structures
16.2K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.2K
Protein Complex Assembly
15.2K
Proteins can form homomeric complexes with another unit of the same protein or heteromeric complexes with different types. Most protein complexes self-assemble spontaneously via ordered pathways, while some proteins need assembly factors that guide their proper assembly. Despite the crowded intracellular environment, proteins usually interact with their correct partners and form functional complexes.
Many viruses self-assemble into a fully functional unit using the infected host cell to...
Many viruses self-assemble into a fully functional unit using the infected host cell to...
15.2K
Resonance and Hybrid Structures
22.9K
According to the theory of resonance, if two or more Lewis structures with the same arrangement of atoms can be written for a molecule, ion, or radical, the actual distribution of electrons is an average of that shown by the various Lewis structures.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
Resonance Structures and Resonance Hybrids
The Lewis structure of a nitrite anion (NO2−) may actually be drawn in two different ways, distinguished by the locations of the N–O and N=O bonds.
22.9K
Classification of Elements and Compounds
71.7K
Pure substances consist of only one type of matter. A pure substance can be an element or a compound. An element consists of only one type of atom, while a compound consists of two or more types of atoms held together by a chemical bond. Elements are classified as atomic or molecular based on the nature of their basic units.
Compounds are pure substances composed of two or more elements in fixed, definite proportions. Compounds are classified as ionic or molecular (covalent) based on the bonds...
Compounds are pure substances composed of two or more elements in fixed, definite proportions. Compounds are classified as ionic or molecular (covalent) based on the bonds...
71.7K
Chemistry of the Cell
46.1K
The cell is chemically composed of water, organic molecules and inorganic ions.
Water
The polarity of the water molecule and its resulting hydrogen bonding makes water a unique substance with special properties that are intimately tied to the processes of life. Life originally evolved in an aqueous environment, and most of an organism’s cellular chemistry and metabolism occur inside the aqueous contents of the cell’s cytoplasm. Special properties of water are its high heat capacity...
Water
The polarity of the water molecule and its resulting hydrogen bonding makes water a unique substance with special properties that are intimately tied to the processes of life. Life originally evolved in an aqueous environment, and most of an organism’s cellular chemistry and metabolism occur inside the aqueous contents of the cell’s cytoplasm. Special properties of water are its high heat capacity...
46.1K
Carbon Skeletons
112.7K
Life on Earth is carbon-based, as all macromolecules that make up living organisms contain carbon atoms. All organic compounds have a carbon backbone. Each carbon atom is tetravalent and can bond with four other atoms, making it an extraordinarily flexible component of biological molecules. Because carbon’s valence electrons are stable, it rarely becomes an ion. As the carbon chain increases in length, structural modifications such as ring structures, double bonds, and branching side...
112.7K


