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Updated: Nov 17, 2025

Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
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高度還元型PKSシステムの再構成は,ダイアルキルベンゼン生物合成に6π-電循環が要求されていることを明らかにする

Jie Zhang1, Satoshi Yuzawa1, Wei Li Thong1

  • 1Graduate School of Agricultural and Life Sciences, The University of Tokyo, 1-1-1 Yayoi, Bunkyo-ku, Tokyo 113-8657, Japan.

Journal of the American Chemical Society
|February 12, 2021
PubMed
まとめ

研究者は稀なオダイアルキルベンゼンの生体合成を明らかにした. 彼らは in vitro で化合物1のバイオシンセシスを再構成し,エレクトロサイクラゼとチオエステラーゼのような酵素を含む新しい経路を明らかにしました.

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