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Updated: Nov 16, 2025

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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SmI2:サイクロプロピルケトンとアルキンの触媒化された分子間結合:ケトン構成と反応性との関連

Soumitra Agasti1, Nicholas A Beattie1, Joseph J W McDouall1

  • 1Department of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.

Journal of the American Chemical Society
|February 25, 2021
PubMed
まとめ

この研究では,サマリウム (II) ダイオイド (SmI2) を用いた新しい触媒法が導入され,反応剤の浪費とコストを大幅に削減する. 新種のラジカル・リレー戦略により,コレドクタントなしで,装飾されたサイクロペンテンの効率的な合成が可能になる.

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