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Updated: Nov 13, 2025

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
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Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes

Published on: September 12, 2018

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ヨウ素触媒によって活性化されていないアルケンのダイアステロディバーゲント分子間1,2-ダイアミネーション

Satoshi Minakata1, Hayato Miwa1, Kenya Yamamoto1

  • 1Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan.

Journal of the American Chemical Society
|March 12, 2021
PubMed
まとめ

この研究では,アルケンのステレオ特異的1,2-ダイアミナ化のための新しいヨウ素触媒法が報告されています. このアプローチは,様々なアルケンの1,2-ダイアミンのすべてのダイアステロエーマー形式にアクセスできます.

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Consider the bromination of cyclopentene. Molecular bromine is polarized in the proximity of the π electrons of cyclopentene. An electrophilic bromine atom adds across the double bond, forming a cyclic bromonium ion intermediate.
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