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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

Published on: January 17, 2020

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リガンドの適合性の柔軟性により,フォスフォナート誘導型触媒的非対称アルケンの水酸化でエナチオセレクティブの三次性C-B結合形成が可能

Huiling Shao1,2, Suman Chakrabarty3,4, Xiaotian Qi1

  • 1Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, United States.

Journal of the American Chemical Society
|March 22, 2021
PubMed
まとめ

柔軟なTADDOLリガンドは,Rh触媒による非対称な水酸化を強化し,異なる形状を採用する. これはステリック相互作用を制御し,独特の触媒サイクルステップを通じて反応速度とエナチオ選択性を改善します.

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