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Updated: Nov 9, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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ロンドン分散に基づく新しいリガンド設計は,キラルビスマス-ロジウムパッドルホイール触媒を強力にする

Santanu Singha1, Michael Buchsteiner1, Giovanni Bistoni1

  • 1Max-Planck-Institut für Kohlenforschung, 45470 Mülheim/Ruhr, Germany.

Journal of the American Chemical Society
|April 8, 2021
PubMed
まとめ

シリル改変リガンドを持つ新しいビスムートロジウム触媒は,カーベンの反応において優れた選択性とより速い反応率を示している. ロンドン分散力はキラルリガンド球を安定させ,触媒の性能を高めます.

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