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Updated: Nov 9, 2025

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
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原子移転触媒によるクロス・セレクティブ・アザ・ピナコールカップリング

Sean M Rafferty1, Joy E Rutherford1, Lumin Zhang1

  • 1Department of Chemistry and Biochemistry, The Ohio State University, Columbus, Ohio 43210, United States.

Journal of the American Chemical Society
|April 8, 2021
PubMed
まとめ

新しいクロス選択的アザ-ピナコール結合反応により,アルデヒドとイミンから貴重なβ-アミノアルコールを生成する. このフォトイニシアチブ・マンガネス・カタライズ・メソッドは,セレクティブ・ケチル・ラジカル・カップリングを実現し,望ましくない副作用を回避します.

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