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Updated: Nov 7, 2025

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
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Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine

Published on: June 13, 2022

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ヘチジン型C20-ディテルペノイドアルカロイドの非対称的総合成: (+) -タラシミジンと (+) -タラシミン

Quanzheng Zhang1, Zhao Yang1, Qi Wang1

  • 1Chongqing Key Laboratory of Natural Product Synthesis and Drug Research, School of Pharmaceutical Sciences, Chongqing University, Chongqing 401331, China.

Journal of the American Chemical Society
|May 3, 2021
PubMed
まとめ

この研究は, (+) -タラシミジンと (+) -タラサミン,C20-ディテルペノイドアルカロイドの最初の非対称的全合成を示しています. 主なステップは,キラル・コアを構築するためのサイクロアディションと,Bリングを形成し,重要なヒドロキシル群を設置するための脱オロマティブ・サイクロプロパネーションです.

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