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Updated: Nov 5, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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光触媒C-H活性化と塩素基複合性の微妙な役割

Qiaomu Yang1, Yu-Heng Wang1, Yusen Qiao1

  • 1P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, PA 19104, USA.

Science (New York, N.Y.)
|May 21, 2021
PubMed
まとめ

この研究は,アルコキシラジカルではなく,塩素ラジカルがセリウムベースの光触媒系におけるアルカンC-H活性化を媒介することを明らかにした. この発見は,アルカン機能化におけるラジカルトラッピング実験の以前の解釈を正している.

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