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Updated: Nov 4, 2025

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

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キトンのNi-触媒によるリモート機能化によるZ-シリルエノールエーサーの選択的合成

Sinem Guven1, Gourab Kundu1, Andrea Weßels1

  • 1Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.

Journal of the American Chemical Society
|May 25, 2021
PubMed
まとめ

この研究では,シリルエノールエーテルを合成するための新しいニッケル触媒による遠隔機能化法が導入されています. このプロセスは,チェーンウォーキングを使用してZ選択性を達成し,製品形成を正確に制御します.

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