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Updated: Oct 29, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Published on: April 10, 2015

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すべてを見つけるための1つ:ニオールフェノラート種への一般的な経路

Alessandro Bismuto1, Patrick Müller1, Patrick Finkelstein1

  • 1Laboratorium für Organische Chemie, ETH Zürich, Vladimir-Prelog-Weg 3, HCI, 8093 Zürich, Switzerland.

Journal of the American Chemical Society
|July 12, 2021
PubMed
まとめ

研究者は,ニッケル触媒の限界を克服し,多様なニッケル (I) 複合体を合成するための新しい一般的な方法を開発しました. この突破は,新しい触媒反応の開発のための新しいニッケル (I) 種へのアクセスを可能にします.

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One of the common methods to prepare nitriles is the dehydration of amides. This method requires strong dehydrating agents like phosphorous pentoxide or boiling acetic anhydride for converting amides to nitriles. Another reagent namely, thionyl chloride also accomplishes the dehydration of amides, where amide acts as a nucleophile. The first step of the mechanism involves the nucleophilic attack by the amide on the thionyl chloride to form an intermediate. In the next step, the electron pairs...
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