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Updated: Oct 29, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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フォトレドックス触媒における無害なラジカルイオン中間物質:並列還元方式により,様々なアリル塩化物の結合が可能

Alyah F Chmiel1, Oliver P Williams1, Colleen P Chernowsky1

  • 1Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, United States.

Journal of the American Chemical Society
|July 13, 2021
PubMed
まとめ

この研究は,結合反応のためのアリル塩化物を活性化するために,イソフタロニトリルとナトリウムフォーム酸を使用する新しい光触媒システムを導入しています. このシステムは,二酸化炭素ラジカルアニオン介質を介してアリルラジカルを効率的に生成します.

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