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Updated: Oct 28, 2025

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
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Published on: November 29, 2018

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オレフィンメタテシスの二分子結合:リードおよびエマージングルテニウム-カルベン触媒の相関構造と分解

Daniel L Nascimento1, Marco Foscato2, Giovanni Occhipinti2

  • 1Center for Catalysis Research & Innovation, and Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Canada K1N 6N5.

Journal of the American Chemical Society
|July 16, 2021
PubMed
まとめ

ルテニウム・サイクリック・アルキル・アミノ・カーベンの触媒は,先進的だが,急速に分解する. この研究は,トランス影響メカニズムによる分解の強化を明らかにし,触媒の安定性とオレフィン転移の生産性を向上させる新しい方法を提供します.

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