ディロジウム (II) /キサンフォス触媒によるリレーカルベンの挿入とアリルアルキル化プロセス:反応の発展とメカニズムに関する洞察

Bin Lu1, Xinyi Liang2, Jinyu Zhang1

  • 1State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.

まとめ

この研究は,複雑なα-四次性α-アミノ酸誘導体を合成するための新しいディロジウム (II) /クサンフォス触媒による三成分反応を導入する. この方法は,有機合成における重要な課題を克服し,アリル分子を効率的に組み込みます.

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