超冷却された水中ナノドロップルの低密度の内部は,イオンを地表に放出する
Shahrazad M A Malek1, Victor Kwan2, Ivan Saika-Voivod1,3
1Department of Physics and Physical Oceanography, Memorial University of Newfoundland, St. John's A1B 3X7, Canada.
Journal of the American Chemical Society
|August 10, 2021
まとめ
超冷却水ナノドロップレットでは イオンが表面に押し出されます 室温ではイオンが均一に分散したり 集中したりします これは"静電封じ込め"と呼ばれる現象です
科学分野:
- 物理化学
- コンピュータ化学
- エアロゾール科学
背景:
- エアロゾルの水イオン相互作用は化学反応に影響する.
- 気象や人工エアロゾールには ドロップレット構造の理解が不可欠です
研究 の 目的:
- 水中のナノドロップレットにおけるイオン分布を計算的に調査する.
- 超冷却と室温でのイオン行動の違いを探求する.
- 静電封鎖モデルを用いてイオン行動を分析する.
主な方法:
- 水性ナノドロップルの直接的な計算シミュレーション
- 静電モデルを用いたイオン空間分布の分析.
- 異なる温度でのモデル予測とのシミュレーション結果の比較
主要な成果:
- 超冷却されたナノドロップレットは 低密度のコアを示し コスモトロプイオンを地下に放出します
- 室温では,イオンが均等に分布するか,ドロップレットコアに集中する.
- 静電封じ込めモデルは,室温の振る舞いを正確に予測しますが,超冷却状態ではありません.
結論:
- 超冷却は水性ナノドロップレット内のイオン分布を大幅に変化させます.
- 静電封じ込めは室温で重要な要因ですが,超冷却の振る舞いを説明するには不十分です.
- 発見は,マクロ分子保存のための超冷却 (電気) 噴霧滴を研究するための基礎を提供します.
関連する概念動画
Intermolecular Forces
64.3K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
64.3K
Formation of Complex Ions
24.6K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
24.6K
Colloidal precipitates
1.6K
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
1.6K
Intermolecular Forces in Solutions
35.9K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
35.9K
Aqueous Solutions and Heats of Hydration
15.9K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
15.9K
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
526
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
526


