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Updated: Oct 25, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

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[Ni/Mg] オートゴナルタンデム触媒ポリメリゼーションによる高ステレオ定義の1,4-cis-ポリディーエンの利用

Daniele Fiorito1, Malaury Simon2, Christophe M Thomas2

  • 1Department of Organic Chemistry, University of Geneva, 30 quai Ernest Ansermet, 1211 Geneva, Switzerland.

Journal of the American Chemical Society
|August 11, 2021
PubMed
まとめ

新しい[ニッケル/マグネシウム]触媒によるタンデムポリメリゼーションは,エノール・リン酸を用いて効率的に1,4-cis-ポリデエンを生成します. この方法は,単純なモノマー改変から多様な材料特性を可能にする高い選択性と制御を提供します.

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