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Updated: Oct 22, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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銅触媒によるエナチオセレクティブβ-フッ化物の除去による軸性キラルフッ化物の生成

Thomas J O'Connor1, Binh Khanh Mai2, Jordan Nafie3

  • 1Department of Chemistry, University of California, Berkeley, California 94720, United States.

Journal of the American Chemical Society
|September 1, 2021
PubMed
まとめ

この研究では,プロパルギル二酸化物から軸性キラルモノフッ素素を合成するための新しい銅触媒法が導入されています. この効率的な反応により,高い収穫量とエナチオ選択性が得られ,価値あるキラル化合物への新しい経路が提供されます.

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