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Updated: Oct 21, 2025

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

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1,5-Diaza-3,7-diphosphacyclooctaneリガンドによって促進される触媒アルデヒドとアルコールアリレーション反応

Eric S Isbrandt1, Amrah Nasim1, Karen Zhao1

  • 1Centre for Catalysis Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada.

Journal of the American Chemical Society
|September 3, 2021
PubMed
まとめ

新しいニッケル触媒法により,アリルヨウ酸化物とアルデヒドまたはアルコールを二次アルコールおよびケトンに効率的に合成します. このアプローチは新しいP2N2リガンドを用いて,望ましくない副作用を防止し,多用途の合成を可能にします.

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The reaction begins with the nucleophilic addition between a phosphorus ylide and the carbonyl compound. Due to its carbanionic character,  phosphorus ylide acts as a strong nucleophile and attacks the electrophilic carbonyl group. This generates a charge-separated dipolar intermediate called betaine. The negatively charged oxygen atom and...
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