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Updated: Oct 19, 2025

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
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A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis

Published on: February 16, 2020

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ステレオセレクティブアルキンのヒドロゲン化による異質イソメリゼーショントランス-アルケンは,挫折した水素原子によって媒介される

Weijie Zhang1, Ruixuan Qin1, Gang Fu1

  • 1State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National & Local Joint Engineering Research Center for Preparation Technology of Nanomaterials and National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

Journal of the American Chemical Society
|September 17, 2021
PubMed
まとめ

この研究は,アルキンの水素化による選択的アルケンの生成のための新しいメカニズムを導入し,トランスオレフィンの高収量を達成します. この新しいアプローチは,ステレオ選択性を制御し,過度の水素化を防ぐために,欠陥のある触媒に挫折した水素原子を使用します.

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