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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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二次アサイクリックアミンとケトンの電気化学的エナチオセレクティブ酸化結合

Zhen-Hua Wang1, Pei-Sen Gao1, Xiu Wang1

  • 1Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai 200032, People's Republic of China.

Journal of the American Chemical Society
|September 17, 2021
PubMed
まとめ

この研究は,アミンとケトンからアミノ酸誘導体を合成するための電気化学的方法を導入する. このプロセスは,選択的酸化のためのリドックスメディエーターを使用し,厳しい添加物なしで高い選択性を達成します.

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