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Updated: Oct 19, 2025

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
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Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes

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電気化学的に生成されたエチルヒポクロライト中間体による1,1-ダイトキシエタンへの選択的塩化媒介のクリーンエタノール酸化

Siqi Li1, Bart M Bartlett1

  • 1Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.

Journal of the American Chemical Society
|September 23, 2021
PubMed
まとめ

研究者は,過酸化なしにアルデヒドを生成する選択的アルコール酸化のための新しい方法を開発しました. このアプローチでは,1,1-ディエトキシエタン (DEE) を保護媒介として使用し,エタノール変換において高い効率を達成します.

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Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of...
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