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Updated: Oct 19, 2025

Constructing Thioether/Vinyl Sulfide-tethered Helical Peptides Via Photo-induced Thiol-ene/yne Hydrothiolation
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Constructing Thioether/Vinyl Sulfide-tethered Helical Peptides Via Photo-induced Thiol-ene/yne Hydrothiolation

Published on: August 1, 2018

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システイン由来のチル触媒による非対称ヴィニルサイクロプロパンサイクロアディションの運動分析は,多くの魅力的な非共性相互作用を反映している

Amanda K Turek1, Marcus H Sak1, Scott J Miller1

  • 1Department of Chemistry, Yale University, 225 Prospect Street, New Haven, Connecticut 06520, United States.

Journal of the American Chemical Society
|September 23, 2021
PubMed
まとめ

ペプチド触媒は,自己集積を妨害することによって,ビニルcyclopropane (VCP) のサイクル添加を促進します. このプロセスは速度とエナチオを決定し,選択性に対する触媒構造の重要性を強調しています.

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