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Updated: Oct 18, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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水を加えるだけで: 触媒ヘクサメリコンカプセルの構造由来酸性の調節

David A Poole1, Simon Mathew1, Joost N H Reek1

  • 1Homogeneous, Supramolecular, and Bioinspired Catalysis Group, van't Hoff Institute for Molecular Science (HIMS), University of Amsterdam (UvA), Science Park 904, 1098 XH Amsterdam, The Netherlands.

Journal of the American Chemical Society
|September 30, 2021
PubMed
まとめ

この研究では,アンデシルリゾルシン[4]アレンカプセルの2つの形態が水分量によって異なっていることが明らかになった. この水分を調節することで,ダイエルス-アルダー反応の触媒活性が強化されます.

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