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Updated: Oct 17, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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モリブデンまたはトングステンのd2 スタイレン複合体とd0 1-フェネチリデン類の相互変換

Sumeng Liu1, Maxime Boudjelel1, Richard R Schrock1

  • 1Department of Chemistry, University of California at Riverside, Riverside, California 92521, United States.

Journal of the American Chemical Society
|October 11, 2021
PubMed
まとめ

この研究は,モリブデンとボルンガムの複合体は,特定の酸によって触媒化されたスタイレンと1-フェネチリデンの形態の間に相互変換することを明らかにしています. 反応メカニズムは,フェネチルカチオン中間体におけるアルファ-デプロトネーションを優先して,プロトネーションとデプロトネーションのステップを含む.

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