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Updated: Oct 15, 2025

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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亜鉛触媒によるサイクロプロパノールのβ機能化,エノライズされたホモエノラートによる

Yoshiya Sekiguchi1, Naohiko Yoshikai1,2

  • 1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.

Journal of the American Chemical Society
|October 29, 2021
PubMed
まとめ

この研究は,モリタ・ベイリス・ヒルマン (MBH) 炭酸塩を用いたサイクロプロパノールのβ-アリア化のための新しい亜鉛触媒反応を導入している. このプロセスは,サイクロプロピルと融合したラクトンを生成し,二機能化ケトンの新しい合成経路を提供します.

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