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Updated: Oct 11, 2025

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
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Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes

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アンチアロマティック・ディシクロペンタ[b,g]/[a,f]ナフタレン・アイソマーは,調節可能なダイラディカル特性を持つオープンシェル・シングレット基底状態を示している

Tingting Xu1, Yi Han1, Zhongjin Shen1

  • 1Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543 Singapore, Singapore.

Journal of the American Chemical Society
|November 29, 2021
PubMed
まとめ

研究者らは,安定した核拡張インダセンの同位体であるディサイクロペンタ[b,g]-ナフタレンとディサイクロペンタ[a,f]ナフタレンを合成した. 両方の分子は,グローバルな反芳香性と,オープンシェルのシングレット基底状態を示し,一つの同位体はより強い反芳香性を示している.

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