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Updated: Oct 8, 2025

Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
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Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes

Published on: December 16, 2019

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Bicyclo[3.2.1]オクタンに対する還元性急激無効化戦略:ent-カウランとベイエランディテルペノイドの合成

Junming Zhuo1,2, Chunlin Zhu1,2, Jinbao Wu2

  • 1Graduate School of Peking Union Medical College and Chinese Academy of Medical Sciences, Beijing 100730, China.

Journal of the American Chemical Society
|December 27, 2021
PubMed
まとめ

ダイターペノイドに含まれる複雑なビサイクロ[3.2.1]オクタン構造の合成を簡素化する新しい根絶法. この突破は,効率的な天然製品の準備のためにユニークなTEMPO効果を使用します.

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Cyclohexenones via Michael Addition and Aldol Condensation: The Robinson Annulation

Robinson annulation is a base-catalyzed reaction for the synthesis of 2-cyclohexenone derivatives from 1,3-dicarbonyl donors (such as cyclic diketones, β-ketoesters, or β-diketones) and α,β-unsaturated carbonyl acceptors. Named after Sir Robert Robinson, who discovered it, this reaction yields a six-membered ring with three new C–C bonds (two σ bonds and one π bond).
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Similar to charge conservation in chemical reactions, spin conservation is implicit for radical reactions. Accordingly, the product formed must possess an...
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