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Updated: Oct 8, 2025

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

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タイタニウムの分離可能なアジドクト (II) は,イミドへの分岐した脱酸化経路に従っている

Anders Reinholdt1, Seongyeon Kwon2,3, Mehrafshan G Jafari1

  • 1Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, United States.

Journal of the American Chemical Society
|December 28, 2021
PubMed
まとめ

アダマンチルアジドとチタン複合物の反応により,イミドと安定したアジドが得られます. 製品分布は反応物質の濃度に依存し,アジドからイミドへの変換の複雑なメカニズムを明らかにする.

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