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Updated: Oct 4, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

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2,2'-メチレンディフェノールにおける非圧縮C (アリル) -C (アルキル) 結合の触媒活性化

Jun Zhu1, Yibin Xue1, Rui Zhang1

  • 1Department of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.

Journal of the American Chemical Society
|February 9, 2022
PubMed
まとめ

研究者らは,フェノール内の不張力炭素-炭素結合を裂くためのロジウム触媒方法を開発しました. この触媒性水解は効率的で,スケーラブルで,様々な機能群を許容し,有機合成のための新しいツールを提供します.

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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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