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Updated: Oct 1, 2025

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

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水素結合相移転触媒による非対称性アジデーション:実験と計算を組み合わせた研究

Jimmy Wang1, Matthew A Horwitz1, Alexander B Dürr1

  • 1Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, U.K.

Journal of the American Chemical Society
|March 1, 2022
PubMed
まとめ

この研究では,低コストのナトリウムアジドを用いた非対称な触媒性アジデーションを,水素結合相移転触媒 (HB-PTC) により実証した. チラルビスウレア触媒は窒素を含む分子のエナチオセレクティブ合成を可能にします.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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